Unit I: First and Second Laws 1 Chapter 1: Basic Concepts 3 Chapter 2: The Energy Balance 39 Chapter 3: Energy Balances for Composite Systems 93 Chapter 4: Entropy 127 Chapter 5: Thermodynamics of Processes 197 Unit II: Generalized Analysis of Fluid Properties 221 Chapter 6: Classical Thermodynamics — Generalizations for Any Fluid 223 Chapter 7: Engineering Equations of State for PVT Properties 249 Chapter 8: Departure Functions 299 Chapter 9: Phase Equilibrium in a Pure Fluid 331 Unit III: Fluid Phase Equilibria in Mixtures 363 Chapter 10: Introduction to Multicomponent Systems 365 Chapter 11: An Introduction to Activity Models 407 Chapter 12: Van der Waals Activity Models 459 Chapter 13: Local Composition Activity Models 493 Chapter 14: Liquid-Liquid and Solid-Liquid Phase Equilibria 531 Chapter 15: Phase Equilibria in Mixtures by an Equation of State 571 Chapter 16: Advanced Phase Diagrams 605 Unit IV: Reaction Equilibria 631 Chapter 17: Reaction Equilibria 633 Chapter 18: Electrolyte Solutions 685 Chapter 19: Molecular Association and Solvation 759
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